Tellurium - Te

General Information

Discovery

Tellurium was discovered by Baron Muller von Reichenstein in 1783 in Sibiu, Romania. Klaproth isolated the element and named it in 1798.

Appearance

Crystalline tellurium is a silvery-white colour with a metallic lustre, but is most often seen as the grey, powdery amorphous form.

Source

Tellurium is present in the Earth's crust only in 0.001 parts per million. It is obtained commercially from the anode muds produced during the electrolytic refining of copper.

Uses

Tellurium is used in alloys, mostly with copper and stainless steel, to improve their machinability. When added to lead it decreases the corrosive action of sulfuric acid on lead and improves its strength and hardness. Tellurium is also used in ceramics. It can be doped with silver, gold, copper or tin in semiconductor applications.

Biological Role

Tellurium has no known biological role. It is very toxic and teratogenic. Workmen exposed to very small quantities of tellurium in the air develop "tellurium breath", which has a garlic-like odour.

General Information

Tellurium burns in air or oxygen with a greenish-blue flame, forming tellurium(IV) oxide. It is unaffected by water or hydrochloric acid, but reacts with nitric acid. Tellurium is a p-type semiconductor, and its conductivity increases slightly with exposure to light. Molten tellurium corrodes iron, copper and stainless steel.




  Physical Information    
  Atomic Number   52
  Relative Atomic Mass (12C=12.000)   127.6
  Melting Point/K   722.7
  Boiling Point/K   1263
  Density/kg m-3   6240 (293K)
  Ground State Electron Configuration   [Kr]4d105s25p4
  Electron Affinity(M-M-)/kJ mol-1   -190.2


  Key Isotopes          
  nuclide 120Te 122Te 123Te 124Te 125Te
  atomic mass 119.9 121.9 122.9 123.9 124.9
  natural abundance 0.096% 2.6% 0.908% 4.816% 7.18%
  half-life stable stable 1.2x1013 yrs stable stable
 
  nuclide 126Te 127Te 128Te 130Te  
  atomic mass 125.9   127.9 129.9  
  natural abundance 18.95% 0% 31.69% 33.8%
  half-life stable 9.4 h stable stable  

s

Other Information  
Enthalpy of Fusion/kJ mol-1 13.5
Enthalpy of Vaporisation/kJ mol-1 104.6
     
Oxidation States  
main Te+4
others Te-2, Te-1, Te0, Te+2,
  Te+5, Te+6
   
Covalent Bonds /kJ mol-1  
Te - H 240  
Te - O 268  
Te - F 335  
Te - Cl 251  
Te - Te 235  
  Ionisation Energies/kJ mol-1
  M - M+ 869.2
  M+ - M2+ 1795
  M2+ - M3+ 2698
  M3+ - M4+ 3610
  M4+ - M5+ 5668
  M5+ - M6+ 6822
  M6+ - M7+ 13200
  M7+ - M8+ 15800
  M8+ - M9+ 18500
M9+ - M10+ 21200