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Tellurium - Te General Information Discovery Tellurium was discovered by Baron Muller von Reichenstein in 1783 in Sibiu, Romania. Klaproth isolated the element and named it in 1798. Appearance Crystalline tellurium is a silvery-white colour with a metallic lustre, but is most often seen as the grey, powdery amorphous form. Source Tellurium is present in the Earth's crust only in 0.001 parts per million. It is obtained commercially from the anode muds produced during the electrolytic refining of copper. Uses Tellurium is used in alloys, mostly with copper and stainless steel, to improve their machinability. When added to lead it decreases the corrosive action of sulfuric acid on lead and improves its strength and hardness. Tellurium is also used in ceramics. It can be doped with silver, gold, copper or tin in semiconductor applications. Biological Role Tellurium has no known biological role. It is very toxic and teratogenic. Workmen exposed to very small quantities of tellurium in the air develop "tellurium breath", which has a garlic-like odour. General Information Tellurium burns in air or oxygen with a greenish-blue flame, forming tellurium(IV) oxide. It is unaffected by water or hydrochloric acid, but reacts with nitric acid. Tellurium is a p-type semiconductor, and its conductivity increases slightly with exposure to light. Molten tellurium corrodes iron, copper and stainless steel. |
| Physical Information | |||
| Atomic Number | 52 | ||
| Relative Atomic Mass (12C=12.000) | 127.6 | ||
| Melting Point/K | 722.7 | ||
| Boiling Point/K | 1263 | ||
| Density/kg m-3 | 6240 (293K) | ||
| Ground State Electron Configuration | [Kr]4d105s25p4 | ||
| Electron Affinity(M-M-)/kJ mol-1 | -190.2 |
| Key Isotopes | ||||||
| nuclide | 120Te | 122Te | 123Te | 124Te | 125Te | |
| atomic mass | 119.9 | 121.9 | 122.9 | 123.9 | 124.9 | |
| natural abundance | 0.096% | 2.6% | 0.908% | 4.816% | 7.18% | |
| half-life | stable | stable | 1.2x1013 yrs | stable | stable | |
| nuclide | 126Te | 127Te | 128Te | 130Te | ||
| atomic mass | 125.9 | 127.9 | 129.9 | |||
| natural abundance | 18.95% | 0% | 31.69% | 33.8% | ||
| half-life | stable | 9.4 h | stable | stable | ||
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| Other Information | ||
| Enthalpy of Fusion/kJ mol-1 | 13.5 | |
| Enthalpy of Vaporisation/kJ mol-1 | 104.6 | |
| Oxidation States | ||
| main | Te+4 | |
| others | Te-2, Te-1, Te0, Te+2, | |
| Te+5, Te+6 | ||
| Covalent Bonds /kJ mol-1 | ||
| Te - H | 240 | |
| Te - O | 268 | |
| Te - F | 335 | |
| Te - Cl | 251 | |
| Te - Te | 235 | |
| Ionisation Energies/kJ mol-1 | ||
| M - M+ | 869.2 | |
| M+ - M2+ | 1795 | |
| M2+ - M3+ | 2698 | |
| M3+ - M4+ | 3610 | |
| M4+ - M5+ | 5668 | |
| M5+ - M6+ | 6822 | |
| M6+ - M7+ | 13200 | |
| M7+ - M8+ | 15800 | |
| M8+ - M9+ | 18500 | |
| M9+ - M10+ | 21200 | |
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